Graphene-porphyrin single-molecule transistors.
نویسندگان
چکیده
We demonstrate a robust graphene-molecule-graphene transistor architecture. We observe remarkably reproducible single electron charging, which we attribute to insensitivity of the molecular junction to the atomic configuration of the graphene electrodes. The stability of the graphene electrodes allow for high-bias transport spectroscopy and the observation of multiple redox states at room-temperature.
منابع مشابه
Electron and heat transport in porphyrin-based single-molecule transistors with electro-burnt graphene electrodes
We have studied the charge and thermal transport properties of a porphyrin-based single-molecule transistor with electro-burnt graphene electrodes (EBG) using the nonequilibrium Green's function method and density functional theory. The porphyrin-based molecule is bound to the EBG electrodes by planar aromatic anchor groups. Due to the efficient π-π overlap between the anchor groups and graphen...
متن کاملConduction coefficient modeling in bilayer graphene based on schottky transistors
Nowadays carbon nanoparticles are applied on the island of single electron transistor and Nano-transistors. The basis of single electron devices (SEDs) is controllable single electron transfer between small conducting islands. Based on the important points in quantum mechanics, when a wave passes through several spatial regions with different boundaries, the wave function of the first region di...
متن کاملSurvival of spin state in magnetic porphyrins contacted by graphene nanoribbons
We report on the construction and magnetic characterization of a fully functional hybrid molecular system composed of a single magnetic porphyrin molecule bonded to graphene nanoribbons with atomically precise contacts. We use on-surface synthesis to direct the hybrid creation by combining two molecular precursors on a gold surface. High-resolution imaging with a scanning tunneling microscope f...
متن کاملPreconcentration of Pb(II) by Graphene Oxide with Covalently Linked Porphyrin Adsorbed on Surfactant Coated C18 before Determination by FAAS
A simple, highly sensitive, accurate and selective method for determination of trace amounts of Pb(II) in water samples is presented. A novel Graphene oxide with covalently linked porphyrin solid-phase extraction adsorbent was synthesized by covalently linked porphyrin onto the surfaces of graphite oxides. The stability of a chemically (GO-H2P) especially in concentrated hydrochloric acid was s...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Nanoscale
دوره 7 31 شماره
صفحات -
تاریخ انتشار 2015